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Phase diagrams mean more to the metallurgist than mere graphical records of the physical states of matter. They provide a medium of expression and thought that simplifies and makes intelligible the otherwise bewildering pattern of change that takes place as elemental substances are mixed one with another and are heated or cooled, compressed or expanded. They illumine relationships that assist us in our endeavor to exercise control over the behavior of matter. These are no accidental by-products of a system devised primarily for the recording of physical data. They exist because the basic features of construction of all phase diagrams are dictated by a single natural law, the phase rule of J. Willard Gibbs, which relates the physical state of a mixture with the number of substances of which it is composed and with the environmental conditions imposed upon it. <...>
Copper is most commonly present in the earth’s crust as coppereironesulfide and copper sulfide minerals, such as chalcopyrite (CuFeS2) and chalcocite (Cu2S). The concentration of these minerals in an ore body is low. Typical copper ores contain from 0.5% Cu (open pit mines, Fig. 1.1) to 1 or 2% Cu (underground mines). Pure copper metal is mostly produced from these ores by concentration, smelting, and refining (Fig. 1.2). Copper also occurs to a lesser extent in oxidized minerals (carbonates, oxides, hydroxy-silicates, sulfates). Copper metal is usually produced from these minerals by leaching, solvent extraction, and electrowinning (Fig. 1.3). These processes are also used to treat chalcocite (Cu2S). A third major source of copper is scrap copper and copper alloys. Production of copper from recycled used objects is 10 or 15% of mine production. In addition, there is considerable re-melting/re-refining of scrap generated during fabrication and manufacture. Total copper production in 2010 (mined and from end-of-use scrap) was ~20 million tonnes. <...>
This book describes extraction of nickel, cobalt and platinum-group metals. The starting point is ore-in-place and the finishing point is high-purity metals and chemicals. We have combined the description of these metals in one book because they very often occur together, are extracted together and have similar properties. The objectives of the book are to:
(a) describe how these metals occur and are extracted; (b) explain why these extraction processes have been chosen; (c) indicate how the processes can be operated most efficiently, with minimal impact on the environment; and, (d) suggest future improvements.
Extractive metallurgy is that branch of metallurgy that deals with ores as raw material and metals as finished products. It is an ancient art that has been transformed into a modem science as a result of developments in chemistry and chemical engineering. The present volume is a collective work of a number of authors in which metals, their history, properties, extraction technology, and most important inorganic compounds and toxicology are systematically described.
Extractive metallurgy is that branch of metallurgy that deals with ores as raw material and metals as finished products. It is an ancient art that has been transformed into a modem science as a result of developments in chemistry and chemical engineering. The present volume is a collective work of a number of authors in which metals, their history', properties, extraction technology, and most important inorganic compounds and toxicology are systematically described.
Extractive metallurgy is that branch of metallurgy that deals with ores as raw material and metals as finished products. It is an ancient art that has been transformed into a modem science as a result of developments in chemistry and chemical engineering. The present volume is a collective work of a number of authors in which metals, their history, properties, extraction technology, and most important inorganic compounds and toxicology are systematically described.
The aim of this book is to summarize the current state of knowledge on the environmental geochemistry and resource potential of metallurgical slags. Hundreds of millions of tonnes of slag, a by-product of pyrometallurgical processing of ferrous and non-ferrous ores or recyclable materials, are generated annually worldwide. These slags are either landfilled, reprocessed, or repurposed.
The term rare earths denotes the group of 17 chemically similar metallic elements that includes scandium, yttrium, and the lanthanides (Spedding 1978; Connelly et al. 2005). The lanthanides are the series of elements with atomic numbers 57 to 71, all of which, except promethium, occur in nature. The rare-earth elements, being chemically similar to one another, invariably occur together in minerals and behave as a single chemical entity. Thus, the discovery of the rare earths themselves occurred over a period of nearly 160 years, from 1787 to 1941 (Szabadvary 1988; Weeks 1956).
Reports of economic crises, investor anxiety and the impact of climate change al help paint a gloomy picture of the future. More optimistic predictions may be met with scorn and accused of lack of ‘reality.’ Nonetheless, one of the many lessons of history is that accurate factual data provides by far the best basis for discussion of future alternative paths of development, optimistic or otherwise (Raw Materials Database 2012). The objectives of this paper are to show: (1) that positive future trends related to mining and metals are evident (Ericsson and Hodge 2012); and (2) that a number of gloom-laden myths should be refuted