Книга является первой обобщающей монографией по минералогия самородной серы и парагенных ей минералов (кальцита, арагонита, целестина, барита, гипса, киарца и его разновидностей, пирита и др.) Основное внимание уделено самородной сере. Детально рассмотрена ее структура, химический состав, физические свойства, морфология, рост и изменение реальных кристаллов, морфология и онтогения агрегатов, типоморфные особенности. На основании анализа состава к строения серы и парагенных ей минералов, изучения пар а генетических соотношений минералов и зональности серных тел рассмотрена история минералогенезиса в месторождениях самородной серы, выяснены физико-химические особенности сероотлагающих растворов, высказаны соображения о генезисе месторождений. В заключение рассмотрены поисково-оценочные минералогические критерии на самородную серу.

Вопрос о возрасте, самостоятельности и месте малых интрузий в истории развития юго-западных отрогов Гиссара до настоящего времени не рассматривался исследователями. В существующих схемах магматизма указанного района они относились к дайковым образованиям, венчающим герцинский цикл  (2).

В результате проведенных исследований нами в пределах хр. Сурхантау, Северного Байсунтау, Чакчара откартирована и изучена серия пород (диорит-порфириты, гранодиорит-порфиры, гранит-порфиры и др.), относящихся к разряду малых интрузий. При этом под малыми интрузиями мы подразумеваем «комплекс интрузивных пород, состоящий из родственных, но самостоятельных тел, которые обычно образуются в поздние этапы развития магматизма определенного цикла» (3).

The Carlin disseminated gold deposit occurs in an autochthonous sequence of Paleozoic sedimentary rocks exposed in a structural window in the Roberts Mountains thrust in north-central Nevada. The upper 175 m of the Silurian Roberts Mountains Formation hosts the majority of ore at Carlin and is characterized by laminated, fine-grained, calcareous and/or dolomitic argillaceous siltstone with local coarser grained siltstones and <0.25- to >50-cm-thick lenticular interbeds of sand- and granule-sized calcareous bioclastic debris or fossil hash. Detailed studies of drill core and exposures in the East pit of the Carlin mine show that alteration and mineralization are zoned away from crosscutting fault conduits and these more permeable bioclastic beds, indicating that these two features were major inflow zones for hydrothermal fluid.

In unoxidized rocks, unaltered calcareous siltstone (1) containing quartz, dolomite, calcite, illite, K feldspar, and pyrite is progressively converted to assemblages of (2) quartz + dolomite + calcite + illite + pyrite, (3) quartz + dolomite + illite-K mica + pyrite, (4) quartz + illite-K mica + pyrite, and (5) quartz + kaolinite-dickite + pyrite adjacent to inflow zones where jasperoids are developed. Gold most consistently enriches the zone of calcite and dolomite removal (3 and 4 above), though it occurs in all zones, locally in high concentrations. This zoned alteration was accomplished by a C02-rich acidic fluid. This acidic alteration enhanced the passage of fluids by extensive carbonate removal to form zones of higher permeability.

Oxidation is wholly a supergene effect related to deep weathering, because the oxidation is superimposed on both mineralized and altered rocks with only minor effect on the major element chemistry; it has produced low-temperature goethitic Fe oxides rather than higher temperature hematite and is not spatially related to Au distribution at the mine or on a district scale.

Because of extensive carbonate removal leading to local volume reduction through collapse and/or compaction, geochemical effects are examined using ratios to relatively immobile elements such as Al and Ti. Extensive depletion of Ca, Mg, and C02 and introduction of Si, Au, and S have occurred. Potassium is depleted in the conversion of illite to dickite-kaolin-ite in proximal silicified inflow zones, and Fe enriches some pyritized rock. Carbonate removal and silicification are two separate processes, both of which are spatially associated with mineralization. Mineralized decarbonated rocks and barren footwall rocks commonly are not silicified, and intensely silicified proximal alteration zones are generally low grade.

Geologic relationships, major element data, and isotopic geochemistry of a group of Carlin-type Au deposits in the Alligator Ridge-Bald Mountain district of east-central Nevada were investigated to help constrain the origin and relative timing of Au mineralization and associated alteration. The Vantage gold deposits were the largest of 18 known sediment-hosted, disseminated gold deposits and prospects that are distributed over a strike length of 40 km. The district consists predominantly of Paleozoic carbonate and siliciclastic sedimentary rocks. Minor amounts of Tertiary volcanic and volcanic-related sedimentary rocks and a small granitic stock in the northern end of the district are also present. The intrusion and its surrounding aureole also host gold mineralization, but most gold deposits in the district are not spatially associated with intrusive rocks.

The Carlin gold deposit, largest of the epithermal disseminated replacement-type gold deposits discovered to date in the United States, formed as a result of hydrothermal processes associated with a shallow-seated late Tertiary igneous event. The orebodies formed by the replacement of carbonate minerals, principally calcite, in thin-bedded argillaceous arenaceous dolomitic beds favorable for mineralization within the upper 245+ m of the Roberts Mountains Formation. Early hydrothermal fluids dissolved calcite and deposited quartz. Fluids during the main hydrothermal stage introduced Si, Al, K, Ba, Fe, S, and organic materials, plus Au, As, Sb, Hg, and Tl; quartz and pyrite were deposited, potassium clays formed, and more calcite was dissolved. Sulfides and sulfosalts containing As, Sb, Hg, and Tl, and base metal sulfides of Pb, Zn, and Cu probably formed later in the paragenesis.

The main stage of ore deposition was terminated with the deposition of barite veins and the onset of boiling. The fluids lost H20, C02, H2S, and other components, leading to the production of H2S04 in the upper levels of the deposit and to subsequent intense acid leaching and oxidation of rocks and ore near the surface. Within this zone, calcite and large amounts of dolomite were removed, sulfides and organic compounds oxidized, kaolinite and anhydrite formed, and silica was added. After the hydrothermal event, the upper part of the deposit underwent weak oxidation by cooler ground water.

Gold has been discovered recently at Cortez, Nevada, about 45 miles southwest of Carlin in carbonate rocks in a window of the Roberts Mountains thrust. The host rock consists of laminated to thin-bedded dark- to light-gray, silty dolomitic limestone and calcareous dolomitic siltstone in the upper part of the Silurian Roberts Mountains Limestone. These rocks contain sparse pyrite cubes and aggregates and some organic carbon. The rocks have been faulted and folded repeatedly during their complex geologic history. The gold is disseminated in a large zone where the rocks have been fractured and bleached and the pyrite oxidized. During oxidation the iron was redistributed, giving the rock a color ranging from light gray to dark red. The alteration zone envelops a 34-m.y.-old intrusive body of biotite-quartz-sanidine porphyry, which is also altered. No genetic relationship between the mineralization and the intrusive body is known. Silicification, iron-oxide staining, decalcification and, in extreme cases, dedolo-mitization generally accompanied the gold metallization, although any one of these phases of hydrothermal alteration may have been well developed without introduction of significant amounts of gold. Some clay alteration occurred in the igneous rock but none in the ore body. The gold is in micron-sized particles of native gold. Gold is mostly with silica between original silt grains and to a lesser extent in quartz-filled microfractures and hematite-goethite pseudomorphs after pyrite.

The gold was discovered during the examination of an arsenic-antimony-tungsten-mercury geochemical anomaly known in the area. Other gold deposits in north-central Nevada are associated with such anomalies.

The Getchell veins are lenticular replacement bodies lying along arcuate branches of a complex range-front fault system. The fault zone cuts all rocks of the district and is tentatively dated as late Tertiary.

The more intensely mineralized portions of the deposit form a shallow blanket with roots that project downward into areas of sparse mineralization.    The gold shoots are restricted to areas of intense mineralization.

Native gold and native silver are the only economic minerals. The great bulk of the gold occurs in minute but microscopically visible particles. Some gold may also occur in submicroscopic particles and some may be in solid solution in pyrite and carbon.

The ore minerals, dissolved in alkali sulfide solutions, are believed to have been deposited when the sulfide ion concentration in the hydrothermal liquid decreased, making unstable the double sulfides of gold-, iron, and arsenic.

The Getchell deposit is similar in many ways to the Nevada quicksilver deposits and present-day hot-spring deposits. The Getchell ore occurrence may represent a gradation from the common epithermal gold deposit to the cinnabar deposit. It is therefore placed close to the feeblest end of the epithermal group.

Most of the ore deposits of the Manhattan district are gold-bearing veins of a simple type and present no unusual features, but other ores inclosed in a single thin bed of limestone offer interesting problems.

Manhattan is situated in the southern part of the northeasterly trending Toquima Range, about 35 miles north of Tonopah. The Toquima Range is one of the less prominent of the many narrow, isolated mountain ranges which are such notable features of the Great Basin topography. The range is bordered by desert valleys—Ralston Valley and Monitor Valley on the east and Big Smoky Valley on the west. On both sides, but particularly on the west, the boundary between rock in place and valley fill is irregular, in marked contrast to the sharp lines of demarcation on the eastern front of the Toyabe Range, which borders Big Smoky Valley on the west.

Geochemical orientation surveys were completed over covered Carlin-type gold deposits in the Cortez mine area with the expressed aim of identifying and evaluating exploration methods to discover Au ore under transported alluvial cover in Nevada. Orientation tests were designed to assess the utility of geochemical applications at various scales of exploration, both drill targets at the deposit scale and “footprints” associated with deposits at the district scale.

Detailed surveys were completed over the covered Gap deposit, located adjacent to the giant Pipeline deposit. Both Carlin-type gold mineralization and earlier, spatially associated, base metal skarn mineralization at Gap were located by soils, soil gas, and vegetation. Loam soils at 6- to 12-cm depth provided a consistent and uniformly available sample medium. Gold ore under 10 m of cover in the northern portion of the Gap deposit was readily detected by analysis of Au by fire assay and ultra trace aqua regia methods in the -80 mesh fraction of these loam soils. Arsenic anomalies occur over the northern end and over the main ore zone at Gap, where there is 25 to 50 m of alluvial cover. Zinc concentrations in soil show the most coherent spatial relationship with underlying Au ore. Tests of MMI-B and Enzyme Leach selective leaches did not result in significant enhancement of the anomalies relative to aqua regia. CO2 and O2 in soil gas indicate faults and underlying mineralized carbonates at Gap, where weathering reactions likely generated CO2 from acid reaction with carbonate. Elevated Au and As in mixed sagebrush and shadscale occur over most ore zones, with the highest Au concentrations over the main ore zone rather than the shallowly buried northern zone. Like soils, elevated Zn in vegetation shows the most coherent spatial relationship with underlying ore.

This study was undertaken to characterize the mineral paragenesis and metal zoning at the property scale, evaluate the potential sources of ore-related metals, quantify the relationship between intensity of alteration and gold grade, and propose a comprehensive genetic model for the Carlin-type Au deposits at the southern part of the Goldstrike property, Nevada.

Mineralogy, textural relationships, whole-rock composition, and spatial distribution of the studied samples revealed two types of gold ore: Ore I and II. The former, which is hosted by the Roberts Mountains and Rodeo Creek Formations, and the Wispy, Planar, and Upper Mud units of the Popovich Formation, is the most abundant and widespread in the property. Ore I is characterized by intense hydrothermal alteration (e.g., carbonate dissolution, silicification, and precipitation of pyrite) and high amounts of trace elements (e.g., Ag, As, Au, Ba, Cd, Cu, Hg, Mo, Ni, S, Sb, Se, Te, Tl, and Zn). On the other hand, Ore II, which is hosted in the Wispy, Planar, and Soft Sediment Deformation units of the Popovich Formation, is mainly confined to the central-north-northwest portion of the Screamer deposit and is weakly altered with low concentration of trace elements. Both Ores I and II contain similar average concentrations of Au in whole rock (14 and 19 g/t Au, respectively) and in pyrite (290 and 540 ppm, respectively); however, auriferous pyrite from Ore I has higher trace element (As, Ag, Cu, Hg, Ni, Sb, Se, and Tl)/Au ratios than Ore II.