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Skutterudites have been the subject of keen scientific studies for the past 40 years or so. The interest was precipitated by the discovery of Prof. Wolfgang Jeitschko and his colleagues (1977), revealing that an open structure of skutterudites typified by two large voids in the unit cell can be filled with foreign species (ions), giving rise to what are called filled skutterudites. Throughout the years, it has been shown that the filling dramatically modifies the physical properties of the original binary form of skutterudites and gives rise to a plethora of fascinating electronic, magnetic, and superconducting characteristics.