In the Late Cambrian-Ordovician, Gondwana-derived microcontinents such as Kokchetav, Altai-Mongolian, Tuva-Mongolian, and Barguzin, as well as the Kazakhstan-Tuva-Mongolian island arc or a system of island arcs were involved in intense accretion-collision processes in similar geodynamic settings on a vast territory of Central Asia — from West Kazakhstan to Lake Baikal. The processes were likely to be the result of a large rebuilding of the Earth’s crust possibly related to the increased mantle impact on the lithosphere as they were simultaneous to the opening of the Uralian and Mongolian-Okhotsk (Turkestan) Oceans. The 970–850 Ma breakup of Rodinia and the 760–700 Ma important tectonic events were followed by the Late Cambrian-Early Ordovician plume magmatism impulse at 500–480 Ma, which led to the opening of new oceans and accelerated the accretion of the Gondwana-derived blocks to the island arc and subsequent formation of an extended — more than 6000 km long — Kazakhstan-Baikal orogenic belt.

The following structural elements have been recognized to constitute the tectonic demarcation of Central Asian Foldbelt: (1) The Kazakhstan–Baikal composite continent, its basement formed in Vendian–Cambrian as a result of Paleoasian oceanic crust, along with Precambrian microcontinents and Gondwana-type terranes, subduction beneath the southeastern margin of the Siberian continent (western margin in present-day coordinates). The subduction and subsequent collision of microcontinents and terranes with the Kazakhstan–Tuva–Mongolia island arc led to crustal consolidation and formation of the composite-continent basement. In Late Cambrian and Early Ordovician, this continent was separated from Siberia by the Ob’–Zaisan ocean basin. (2) The Vendian and Paleozoic Siberian continental margin complexes comprising the Vendian–Cambrian Kuznetsk–Altai island arc and the rock complexes of Ordovician–Early Devonian passive margin and Devonian to Early Carboniferous active margin. Fragments of Vendian–Early Cambrian oceanic crust represented by ophiolite and paleo-oceanic mounds dominate in the accretionary wedges of island arc. The Gondwana-type continental blocks are absent in western Siberian continental margin complexes and supposedly formed at the convergent boundary of a different ocean, probably, Paleopacific. (3) The Middle–Late Paleozoic Charysh–Terekta–Ulagan–Sayan suture-shear zone separating the continental margin complexes of Siberia and Kazakhstan–Baikal. It is composed of fragments of Cambrian and Early Ordovician oceanic crust of the Ob’–Zaisan basin, Ordovician blueschists and Cambrian–Ordovician turbidites, and Middle Paleozoic metamorphic rocks of shear zones. In the suture zone, the Kazakhstan–Baikal continental masses moved westward along the southeastern margin of Siberia. In Late Devonian and Early Carboniferous, the continents amalgamated to form the North Asian continent. (4) The Late Paleozoic strike-slip faults forming an orogenic collage of terranes, which resulted from Late Devonian to Early Carboniferous collision between Kazakhstan–Baikal and Siberian continents and Late Carboniferous to Permian and Late Permian to Early Triassic collisions between East European Craton and North Asian continent. As a result, the Vendian to Middle Paleozoic accretion-collisional continental margins of Siberia and the entire Kazakhstan–Baikal composite continent became fragmented by large-amplitude (up to a few thousand kilometers) strike-slip faults and conjugate thrusts into several strike-slip terranes, which mixed with each other and thus disrupted the original geodynamic, tectonic, and paleogeographic demarcation.

Central Mongolia is geologically characterized by close juxtaposition of an accreted oceanic terrane with an arc-microcontinent collision zone. We present new U–Pb zircon ages and geochemical data for the Bayankhongor ophiolite mélange from the oceanic terrane and for a syenite porphyry pluton from the arc-microcontinent zone, providing critical constraints on the regional evolution in late Neoproterozoic to early Cambrian times. An anorthosite (655±4 Ma) associated with layered gabbro, a rodingite (metasomatized layered gabbro) (647±6 Ma), and a high-level isotropic amphibole gabbro (647±7 Ma) yielded the oldest zircon ages for the plutonic part of the ophiolite. A plagiogranite dike in the amphibole gabbro yielded an age of 636±6 Ma, which is the youngest date obtained for the ophiolitic rocks. We suggest that the long duration (ca. 20 Ma) for formation of this plutonic sequence characterizes the sea-floor spreading evolution, and the Nd–Sr isotopic composition (εNd(t) = +7.6 to +4.7; initial 87Sr/86Sr ratio = 0.70279–0.70327) points to a mid-ocean-ridge origin. The syenite porphyry, dated at 523±2 Ma, records the terminal or post-collisional phase of orogeny. The Bayankhongor oceanic lithosphere experienced at least 92Ma of drift between its formation and accretion.