A rapid field analytical method for gold in geochemical exploration

A rapid field method for gold analysis in geochemical exploration has been developed. Cold extraction of Au, at room temperature, using a mixture of sodium bromide, sulphuric acid, hydrogen peroxide is performed; the technique has the advantage of avoiding the irritating odour of commonly used aqua regia digestion. Polyurethane foam is used to concentrate gold from solution. After desorption of Au using mixed reagents (0.5% Na2S03-NaCl solution at pH 8), two sequential procedures, depending on the concentration, are followed for the determination of gold. (1) A 1 mL portion of desorbed solution is used to form Au-TMK-DBS (Thio Micher's Ketone and dodecyl benzene sodium sulphonate) ternary complex. Concentrations below 20 ng/g Au are determined by visual colour comparison of the organic layer with a series of standards. (2) If the concentration is greater than 20 ng/g Au, a complexation reaction using the same reagents is followed by fibre-optic colorimetry. The method is rapid and simple, and the tiresome operation of ashing the foam is avoided. The limit of detection is 0.5 ng/g Au and eighty determinations can be made in one working day. The method could be used for rapid follow-up of rock sample or in situ drill core analyses. About 600 samples from 5 gold districts were tested by this method. The results are very satisfactory.