Optically anomalous crystals / Оптические аномалии в кристаллах

The most striking features of crystals are their symmetric, polyhedral forms. Federov said that crystals “flash-forth their symmetry” (Shubnikov and Kopstik, 1974), a strong allusion to the sharp, highly reflecting surfaces of well-formed crystals prized by enthusiasts. We learned from Häuy that the shapes of crystals reflect the arrangements of the particles from which they are constructed. Today, these arrangements are routinely deduced from x-ray diffraction patterns. In the 19th Century, prior to the discovery of x-rays, the perturbations to the state of visible light traversing a crystal were used to assay symmetry.

Ideally, the symmetry of a crystal that an investigator would deduce from shape, from the transmission of visible light, from the scattering of x-rays, or from any other method, should be the same. However, as early as 1818, David Brewster in Edinburgh first noticed that some crystals appeared to have lower optical symmetries than morphological symmetries (Brewster, 1818b). <...>